The order of features is important. The calt (or whichever feature is carrying the sub rule) must come afterliga (or whatever ligature feature you are using).
Don’t forget to compile your features before testing them.
And how are you testing it? In Glyphs? Then you must activate the features in the lower left corner? Outside of Glyphs: Are you using the Adobe Fonts folder?
@mekkablue
following up question:
It worked out to move the second ligatur to the left but now I am battling with the 3rd
so
Ligatur +Ligatur +Ligatur’
which should also be on -79
You will have to dig a little deeper into AFDKO code. You may want to separate phases of the substitutions into separate lookups. Read the tutorials, and perhaps also read Tal Leming’s OT Cookbook. Check what gets substituted for what (test it in Edit view), so you know what to substitute in the next line of code.